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Creators/Authors contains: "O’Neil, Gregory W"

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  1. ; ; ; ; (, The Journal of Organic Chemistry)
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  2. ; ; (, The Journal of Organic Chemistry)
  3. ; (, Tetrahedron)
    null (Ed.)
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  4. ; ; (, Synthesis)
    SmI2(H2O)n reductions of allylic benzoates adjacent to a trisubstituted alkene occur in high yields with complete regioselectivity and good diastereoselectivity (up to 90:10) for substrates containing properly positioned stereodirecting- and chelating groups. The outcome of these reactions can be rationalized by ring conformation considerations of a proposed chelated organosamarium intermediate, and a mechanism involving intramolecular protonation by a samarium-bound water. 
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  5. ; ; ; ; ; ; ; ; (, Environmental Science & Technology)
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